Interfacial polymerization of poly(2,5‐dimethoxyaniline) and its enhanced capacitive performances

The poly(2,5‐dimethoxyaniline) (PDMA) were synthesized through interfacial polymerization method using three various organic solvent/water reaction systems. As comparison with conventional chemical polymerized PDMA, the interfacial polymerization can produce uniform nanoparticular PDMA, especially for using high density (higher than water) solvent as organic phase. The capacitive performances of interfacial polymerized PDMA can be benefited from its uniform morphologies and loose packing structure. The specific capacitance of interfacial polymerized PDMA using carbon tetrachloride is 194 Fg^?1 at current density of 50 mA cm^?2, which has 59% enhancement over 122 Fg^?1 of conventional PDMA at the same current density. The energy density of interfacial polymerized PDMA is 39 Wh kg^?1 at current density of 5 mA cm^?2 and the power density is 28,421 W kg^?1 at current density of 50 mA cm^?2. The energy density has improvement in different extent as comparison with that of conventional PDMA. The enhanced capacitive performances can be attributed to the increased ionic conductivity induced by the loose molecular packing structure and uniform morphology produced by the interfacial polymerization process. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40666.     

Effect of nanocarbon sources on microstructure and mechanical properties of MgO–C refractories

A study of microstructural evolution, mechanical and thermo-mechanical properties of MgO–C refractories, based on graphite oxide nanosheets (GONs), carbon nanotubes (CNTs) and carbon black (CB), was carried out by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS), three-point bending and thermal shock tests. Meanwhile, these results were compared to the conventional MgO–C refractory containing 10 wt% flaky graphite prepared under the same conditions. The results showed that higher cold modulus of rupture was obtained for the composition containing GONs, and the composition containing CNTs exhibited larger displacement after coking at 1000 °C and 1400 °C. Also, the addition of nanocarbons led to an improvement of the thermal shock resistance; in particular, both compositions containing CNTs and CB had higher residual strength ratio, approaching the thermal shock resistance of the reference composition containing 10 wt% flaky graphite, as it was associated with the presence of nanocarbons and in-situ formation of ceramic phases in the matrix.     

Joining of Si3N4 to Si3N4 using a AuPd(Co,Ni)–V filler alloy and the interfacial reactions

Au38.0–Pd28.0–Co18.0–Ni7.0–V9.0 (in wt%) alloy was designed as a filler for joining Si₃N₄. The filler alloy showed a contact angle of 77.2° on Si₃N₄ ceramic at 1473 K. The Si₃N₄/Si₃N₄ joint brazed with the rapidly-solidified filler foils at 1443 K for 10 min exhibits an average three-point bend strength of 320.7 MPa at room temperature and the strength values are 217.9 MPa and 102.9 MPa at 1073 K and 1173 K respectively. The interfacial reaction products were composed of V₂N and Pd₂Si, and the elements Co and Ni in the brazing alloy did not participate in the interfacial reactions. The coarse-network-like distribution of refractory Pd₂Si compound within the Au–Pd–Co–Ni alloy matrix throughout the joint contributes to the stable high-temperature joint strengths.     

2-氨基-5-溴-N,3-二甲基苯甲酰胺的合成工艺研究

以3-甲基-2-硝基苯甲酸为原料,经酰氯化、甲胺化、FeO(OH)催化水合肼还原、双氧水/氢溴酸氧化溴化,得到目的产物2-氨基-5-溴-N,3-二甲基苯甲酰胺,目标产物及中间体经1 H NMR进行了结构确证,四步反应总收率为85%。     

吹膜挤出机的电磁感应加热系统建模与有限元模拟研究

为实现吹膜挤出机在电磁感应加热条件下能效的定量分析,对吹膜挤出机电磁感应加热的三维有限元模型进行了研究,导出了对应于指定机筒和螺杆材料的电流透入深度与电磁感应加热器的各设计参数之间的关系;分析了挤出机的机筒与螺杆等关键部件在电磁感应三段式分区加热条件下的磁场分布、电流密度场分布及焦耳热能分布的相对趋势。结果表明,感应磁场主要分布在机筒内表面,而相应的感应电流主要分布在机筒外层,且当机筒上缠绕的3组匝数相同的电磁感应加热线圈中加载有大小相等、方向相同的交变电流时,电流密度和产生的焦耳热能集中在机筒和螺杆的中部,而适当增加进料段与计量段加热区所对应的两组线圈匝数可获得较为均匀的电磁感应加热效果。相对于电阻式加热,电磁感应加热的能量损耗较小,是一种环保节能的吹膜挤出机加热方式。     

焦炉煤气配加转炉煤气生产甲醇工艺介绍

介绍了焦炉煤气配加转炉煤气生产甲醇的工艺流程及主要技术特点。该工艺开辟了利用转炉煤气的新方法,可充分利用新鲜气的有用成分,具有增产甲醇和降低消耗等优点。     

水泥工程中快速计算设备基础工程量的探讨

随着计算机的普及,各种算量软件涌现,大幅度提高了工程量计算的工作效率。结合工程实际情况,以广联达钢筋计算软件为例,探讨了在水泥工程中对不同类型的基础快速计算工程量的方法。     

水泥及其原材料中碱含量的检测技巧

碱含量的检测是水泥生产和质量控制的重要环节,火焰光度法的检测过程较为复杂繁琐,极易产生误差。简要叙述了火焰光度法检测碱含量的方法原理、检测步骤、结果处理、影响因素及检测技巧等,并重点分析了提高检测准确性的方法和技巧。     

高效脱色絮凝剂的合成及脱色应用研究

实验以双氰胺、甲醛为主要原料,加入不同的催化剂和改性剂,优选合成出两种双氰胺-甲醛类缩聚物脱色絮凝剂;用IR表征其分子结构;研究了絮凝剂用量、pH、混合投加聚合硫酸铁用量条件对脱色效果的影响,得到最佳脱色条件;对酸性大红GR、活性艳红等废水色度脱色率可达93%以上,并对其工业应用价值作简单分析评价。     

测量不确定度评定在油田化学剂检测实验室中的应用

文章就油田化学剂产品常规检测项目的测量不确定度评定为例,阐述检测实验室测量不确定度评定的一般流程,对于不同的检测项目和检测对象,采用不同的评估方法。旨在交流学习,共同推广测量不确定度在检测实验室中的应用,提高检测实验室的检测水平,并与国际接轨。